期刊
CHEMPHYSCHEM
卷 18, 期 22, 页码 3153-3162出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201700737
关键词
electrochemistry; ionic liquids; NMR spectroscopy; solvent effects; water chemistry
资金
- CTI Swiss Competence Center for Energy Research (SCCER Heat and Electricity Storage)
- Russian Foundation for Basic Research [17-03-00602]
- Swiss National Science Foundation (R'Equip project) [206021_157656]
- Swiss National Foundation [200020_172507]
- National Research, Development and Innovation Office of Hungary [NKFI PD-124079]
- Swiss National Science Foundation (SNF) [200020_172507, 206021_157656] Funding Source: Swiss National Science Foundation (SNF)
Room-temperature ionic liquids (RTILs) are promising new electrolytes for efficient carbon dioxide reduction. However, due to their high viscosity, the mass transport of CO2 in RTILs is typically slow, at least one order of magnitude slower than in aqueous systems. One possibility to improve mass transport in RTILs is to decrease their viscosity through dilution with water. Herein, defined amounts of water are added to 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]), which is a hydrophilic RTIL. Electrochemical measurements on quiescent and hydrodynamic systems both indicate enhanced CO2 electroreduction. This enhancement has its origin in thermodynamic/kinetic effects (the addition of water increases the availability of H+, which is a reaction partner of CO2 electroreduction) and in an increased rate of transport due to lower viscosity. Electrochemically determined diffusion coefficients for CO2 in [BMIm][BF4]/water systems agree well with values determined by NMR spectroscopy.
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