4.7 Article

The role of symmetry breaking in the structural trapping of light-induced excited spin states

期刊

CHEMICAL COMMUNICATIONS
卷 53, 期 99, 页码 13268-13271

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07990g

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资金

  1. EPSRC [EP/K012568/1, EP/K012576/1]
  2. National Research Agency [ANR-13-BS04-0002]
  3. Rennes Metropole
  4. CNRS
  5. COST network Explicit Control of Spin States in Technology and Biology (ECOSTBio) [CM1305]
  6. EPSRC [EP/K012568/1, EP/K012940/2, EP/K012576/1] Funding Source: UKRI
  7. Engineering and Physical Sciences Research Council [EP/K012576/1, EP/K012568/1, EP/K012940/2] Funding Source: researchfish
  8. Agence Nationale de la Recherche (ANR) [ANR-13-BS04-0002] Funding Source: Agence Nationale de la Recherche (ANR)

向作者/读者索取更多资源

Light-Induced Excited Spin State Trapping (LIESST) data are reported for seven isostructural solvate salts from the iron(II)/2,6-di(pyrazol-1-yl) pyridine family. A complicated relationship between their spin-crossover T-1/2 and T(LIESST) values may reflect low-temperature thermal and light-induced symmetry breaking, which is shown by one of the compounds but not by two others.

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