期刊
JOURNAL OF PHYSICAL CHEMISTRY A
卷 121, 期 48, 页码 9297-9305出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpca.7b09427
关键词
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资金
- National Science Foundation [1153861, 1559319]
- Div Atmospheric & Geospace Sciences
- Directorate For Geosciences [1559319] Funding Source: National Science Foundation
Laboratory and field measurements have demonstrated that an isoprene-derived epoxide intermediate (IEPOX) is the origin of a wide range of chemical species found in ambient secondary organic aerosol (SOA). In order to explore the potential relevance of a similar mechanism for the formation of monoterpene-derived SOA, nuclear magnetic resonance techniques were used to study kinetics and reaction products of the aqueous-phase reactions of several monoterpene epoxides: beta-pinene oxide, limonene oxide, and limonene dioxide. The present results, combined with a previous study of a-pinene oxide, indicate that all of these epoxides will react more quickly than IEPDX with aqueous atmospheric particles, even under low-acidity conditions. As for a-pinene oxide, the observed products can be mainly rationalized with a hydrolysis mechanism, and no long-lived organosulfate or nitrate species nor species that retain the beta-pinene bicyclic carbon backbone are observed. As bicyclic ring-retaining organosulfate and nitrate species have been previously observed in monoterpene-derived SOA, it appears that monoterpene-derived epoxides may not be as versatile as IEPDX in producing a range of SOA species, and other mechanisms are needed to rationalize organosulfate and nitrate formation.
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