期刊
TETRAHEDRON LETTERS
卷 58, 期 10, 页码 1015-1019出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.01.095
关键词
C-O coupling; Copper catalyzed; Monodentate ligand; Alkyl aryl ether; Aliphatic alcohol
资金
- JSPS (Japan Society for the Promotion of Science) [25460025]
- Grants-in-Aid for Scientific Research [25460025] Funding Source: KAKEN
A new effective copper catalyzed C-O coupling reaction using excess amount of strongly coordinating monodentate ligands was successfully developed. Among the DMAP-type monodentate ligands, 4-pyrrolidinopyridine afforded the best results. The developed reaction is widely applicable for the synthesis of various hindered or acyclic secondary alkyl-aryl ethers. In this study, a novel and remarkable acceleration of the coupling reaction using excess amount of monodentate ligands was discovered. (C) 2017 Elsevier Ltd. All rights reserved.
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