期刊
TETRAHEDRON LETTERS
卷 58, 期 15, 页码 1480-1483出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.02.088
关键词
Manganese-proline catalyst system; Enantioselective synthesis; Metal-coordination; alpha-Hydroxyphosphonates; alpha-Aminophosphonates
资金
- Department of Chemistry, College of Science and Health, William Paterson University (WPU)
- William Paterson University
- Garden State-Louis Stokes Alliance for Minority Participation (GSLSAMP)
A novel manganese/proline-derived catalyst system is reported for the stereoselective synthesis of alpha-hydroxyphosphonates and alpha-aminophosphonates. The reaction proceeded smoothly under mild reaction conditions with efficient reaction times. The resulting products were obtained with high yields and good enantioselectivities (up to 83% ee). (C) 2017 Elsevier Ltd. All rights reserved.
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