4.4 Article

Unprecedented acid-catalyzed Wurtz-type coupling of meso-bromoindodicarbocyanine dyes

期刊

TETRAHEDRON LETTERS
卷 58, 期 34, 页码 3353-3357

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2017.07.043

关键词

Cyanine dyes; Dimerization; Acid catalysis; Mechanism; Boron trifluoride

资金

  1. Spanish Ministry of Economy and Competitive [CTQ2012-36165]
  2. FEDER
  3. Catalonian Government [2014SGR837]
  4. Russian Science Foundation [12.53.1175.2014]

向作者/读者索取更多资源

meso-Bromosubstituted indodicarbocyanine dyes produce dimeric molecules, together with the debrominated species, under acid catalysis. The relationship between the dimerization and hydro-debromination routes depends on the aryl substitution of the dyes. A possible reaction mechanism is also proposed. (C) 2017 Elsevier Ltd. All rights reserved.

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