期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 52, 页码 16645-16649出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201709384
关键词
arenes; C-H insertion; carbenoids; reaction mechanisms; rhodium
资金
- MEXT [JP15H05756, JP16K05694]
- ACT-C from JST [JPMJCR12Z9]
- JSPS fellowship
- Grants-in-Aid for Scientific Research [15H05756, 16K05694, 16J11354] Funding Source: KAKEN
A rhodium(II)-catalyzed reaction of newly prepared 4-acyl-1-sulfonyl-1,2,3-triazoles with benzene, and its derivatives, is investigated. Acceptor/acceptor carbenoids generated from 4-acyltriazoles undergo selective insertion at aromatic C(sp(2))-H bonds in the presence of benzylic C(sp(3))-H bonds to produce N-sulfonylenaminones.
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