期刊
TETRAHEDRON
卷 73, 期 33, 页码 4874-4882出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.05.023
关键词
Molecular motors; Diastereoselective synthesis; Orthogonal protecting groups; Gram-scale synthesis
资金
- European Research Council under the European Community's Seventh Framework Program (FP7)/ERC Starting Grant [257099]
- ANR [ANR-14-CE06-0021]
- China Scholarship Council (CSC)
In this paper we describe a diastereoselective synthesis of highly functionalized and optically pure Feringa's molecular motors. Two types of chemical functions are introduced on the upper and lower parts of the motor, and their orthogonality is investigated. The synthesis is performed on a gram scale and the diastereoisomers are easily separated by a straightforward column chromatography on silica gel. This general synthetic route is of particular interest to implement these molecular motors in devices and materials science. (C) 2017 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据