期刊
TETRAHEDRON
卷 73, 期 38, 页码 5706-5714出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.08.009
关键词
Carbon disulfide; Trithiocarbonate; Dithiocarbonate; Epoxide
资金
- National Natural Science Foundation of China [NSFC 21571087]
- Major Projects of Natural Science Research in Jiangsu Province [15KJA150004]
- PAPD of Jiangsu Higher Education Institution
- TAPP of Jiangsu Higher Education Institution
- State Key Laboratory of Inorganic Synthesis and Preparative Chemistry at Jilin University [2016-01]
Carbon disulfide is an abundant, inexpensive and readily available material. One of the main challenges in the reaction of epoxides with CS2 is to control the chemoselectivity as a variety of compounds would be formed in the reaction. A simple and convenient method toward selectively synthesis of oxathiolane and trithiocarbonate from epoxides with CS2 catalyzed by NHC/LiCI(Br) under the neat conditions has been developed. This catalytic system exhibits excellent activity and selectivity in cycloaddition reactions of carbon disulfide to terminal epoxides. (C) 2017 Elsevier Ltd. All rights reserved.
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