期刊
TETRAHEDRON
卷 73, 期 51, 页码 7233-7238出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.11.019
关键词
Trifluoromethylthiolation; CF3SO2Na; PhPCl2; Indole; Electron-rich aromatics
资金
- National Science Foundation of China [21572158]
A novel transition metal-free route for the direct trifluoromethylthiolation of electron-rich aromatics using CF3SO2Na in the presence of PhPCl2 was developed. More specifically, PhPCl2 was used as both a reducing and a chlorinating reagent for the first time in this CF3SO2Na-based trifluoromethylthiolation reaction. The absence of transition metals and the use of cheap and readily available reagents render this method an alternative and practical strategy for the trifluoromethylthiolation of electron-rich aromatics. (C) 2017 Published by Elsevier Ltd.
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