期刊
TETRAHEDRON
卷 73, 期 12, 页码 1541-1550出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2017.01.053
关键词
Palladium(II); 1,2-Addition; Arylboronic acids; Cyclization reaction; 2-Quinolinones
资金
- National Natural Science Foundation of China [21232006, 21272249]
- Chinese Academy of Sciences
A cationic palladium complex catalyzed arylative cyclization reaction of N-(2-formylaryl)alkynamides with arylboronic acids was developed. This new process provides an efficient way for the synthesis of functionalized 2-quinolinones in good to excellent yields under mild conditions. Some control experiments were conducted to explain the possible mechanism for the formation of the products. (C) 2017 Published by Elsevier Ltd.
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