期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 51, 页码 44641-44648出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b15564
关键词
metal-organic frameworks; surface functionalization; water stability; catecholase biomimetics; hydrophobic coating
资金
- EU (ERC Stg Chem-fs-MOF) [714122]
- Spanish MINECO (Unit of Excellence Maria de Maeztu) [MDM-2015-0538]
- Generalitat Valenciana [GV/2016/137]
- Spanish MINECO
- FPI Scholarship [CTQ2014-59209-P]
- Junta de Andalucia [P10-FQM-6050]
- Spanish Government [MAT2015-70615-R]
- FEDER funds
- CERCA programme/Generalitat de Catalunya
- Severo Ochoa programme of the Spanish Ministry of Economy, Industry and Competitiveness (MINECO) [SEV-2013-0295]
Robust catechol coatings for enhanced moisture tolerance were produced in one step by direct reaction of Hong Kong University of Science and Technology (HKUST) with synthetic catechols. We ascribe the rapid formation of homogeneous coatings around the metal-organic framework particles to the biomimetic catalytic activity of Cu(II) dimers in the external surface of the crystals. Use of fluorinated catechols results in hydrophobic, permeable coatings that protect HKUST from water degradation while retaining close to 100% of its original sorption capacity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据