期刊
TALANTA
卷 167, 期 -, 页码 39-43出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2017.01.078
关键词
MOF derived carbon; Exfoliated porous carbon; Square wave voltammetry; Chloramphenicol
资金
- '1000 Talent Program' (The Recruitment Program of Global Experts)
- National Natural Science Foundation of China [21473247]
- 'Scientific Research Foundation for the New Teacher' of the Harbin Institute of Technology (Shenzhen)
Benefit from the advantages in costless, simplicity and efficiency, solvent exfoliation has been widely used in preparation of two-dimensional nanosheets with enhanced performances in electronics, photonics, and catalysis. In this work, solvent exfoliation was first applied to prepare exfoliated porous carbon (EPC) from an isoreticular metal-organic framework-8 (IRMOF-8) derived porous carbon (DPC). The obtained EPC with high surface area (1854 m(2) g(-1)) and improved dispersibility was used as electrode modifier for glassy carbon electrode (GCE) in square wave voltammetry (SWV) detection of chloramphenicol (CAP). The sensitivity of EPC modified GCE (EPC/GCE) was greatly improved in compare with that of the DPC modification. The corresponding linear ranges are 1 x 10(-8)-1 x 10(-6) mol L-1 and 1 x 10(-6)-4x10(-6) mol L-1. The detection limit was calculated to be 2.9x10(-9) mol L-1 (at a signal-to-noise ratio of 3, S/N=3). In addition, the proposed sensor was successfully applied in the analysis of CAP in honey and achieved satisfying recovery.
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