期刊
NEW CARBON MATERIALS
卷 32, 期 5, 页码 442-450出版社
ELSEVIER
DOI: 10.1016/S1872-5805(17)60133-1
关键词
Activated carbon; Heteroatom-doping; Supercapacitor; Electrochemical performance
资金
- National Natural Science Foundation of China (NSNF) [U1303192]
- Natural Science Fund Project of Xinjiang uighur autonomous region [2012211A108]
Coal-based activated carbons doped with either N or B or a combination of the two were prepared for use as the electrode materials of supercapacitors by ball milling and subsequent activation using Xinjiang non-caking coal, melamine and boric acid as the respective carbon, nitrogen and boron sources. FTIR spectroscopy and XPS reveal that the B and N atoms are substitutionally incorporated into the carbon skeleton. These doped activated carbons contain a large number of mesopores. Cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy show that N- and B- doped activated carbons have a superior capacitance and rate performance to the non-doped one. The B-N co-doped material has the highest specific capacitance of 176 F.g(-1) at 0. 5 A.g(-1), which is attributed to a synergistic effect of B-N co-doping. The capacitance of the co. doped sample re. mains at 96% of the original value after 20 000 cycles.
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