期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 50, 页码 43767-43773出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b16103
关键词
non-noble metal; graphene oxide; electrophoresis; corrosion; magnesium-ion batteries
资金
- Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future [2015M3D1A1069710]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2014R1A6A1030419]
Despite remarkable developments in electrolyte systems over the past decades, magnesium-ion batteries still suffer from corrosion susceptibility and low anodic limits. Herein we describe how graphene oxide (GO), coated onto non-noble metals (Al, Cu, and stainless steel) via- electrophoretic deposition, can solve this problem. In all phenyl complex electrolytes, GO coating results in a significant suppression of corrosion and extends the anodic limits' (up to 4.0 V vs Mg/Mg2+) with no impact on reversible Mg plating/stripping reactions. The same effect of GO coating is also established in magnesium aluminum chloride complex electrolytes. This remarkable-improvement is associated with the electtostatic interaction between the ionic charges of electrolytes and the-surface-functional groups of GO: In addition, GO coating, does not aggravate the cathode performance of Mo6S8, which allows the use of non-noble metals as current collectors. We also discuss, the role of GO in. increasing anodic limits when it is hybridized with alpha-MnO2.
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