期刊
SYNTHESIS-STUTTGART
卷 49, 期 14, 页码 3171-3182出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588995
关键词
tetrahydroquinolines; chromenes; nitrostyrenes; alkylation; electrophilic substitution; Friedel-Crafts reaction
资金
- CSIR-India
- CSIR-India [CSC-0108]
A simple and novel method has been developed for the C6-functionalization of unprotected tetrahydroquinoline with chromenes or beta-nitrostyrenes in aqueous medium to afford novel 6-substituted tetrahydroquinolines. This method is simple and convenient, and has low costs and mild reaction conditions. Regioselectively C6-alkylated products were obtained exclusively from tetrahydroquinoline, without the formation of C5-, C7-, C8-, or N-alkylated products.
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