期刊
SYNTHESIS-STUTTGART
卷 49, 期 8, 页码 1796-1807出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588686
关键词
catalyst; metathesis; ligands; fluorous; activation
资金
- JSPS KAKENHI [26450145]
- Professor Uozumi's JST-ACCEL program
- Grants-in-Aid for Scientific Research [26450145] Funding Source: KAKEN
Various novel Grubbs-Hoveyda second-generation catalysts activated by a fluorous tag on the ligands were prepared. The catalyst bearing the 1-naphthyl group on the bidentate ligand exhibited the highest catalytic activity among the studied catalysts for the ringclosing- metathesis reaction of diethyl 2-allyl-2-( 2-methylallyl) malonate.
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