期刊
SYNTHESIS-STUTTGART
卷 49, 期 21, 页码 4783-4807出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588542
关键词
catalyst-free; solvent-free; hydrophosphination; hydrophosphinylation; phosphine oxides; phosphine sulfides; phosphine selenides; green chemistry
资金
- Council for Grants at the President of the Russian Federation [NSh-7145.2016.3]
- Council for Grants at the President of the Russian Federation [NSh-7145.2016.3]
Traditional methods for C-P bond formation via direct addition of P-H species to unsaturated compounds are usually implemented in the presence of base and metal catalysts or radical initiators in various organic solvents. During the last five years, a novel efficient and general catalyst/initiator- and solvent-free version of the hydrophosphination and hydrophosphinylation of multiple C-C bonds with H-phosphines and their chalcogenides has begun to develop and it is attracting growing attention. This approach corresponds to the recently emerged pot-, atom-, and step-economy (PASE) green paradigm. This review covers the literature on the synthesis of useful and in-demand organophosphorus compounds via catalyst- and solvent-free addition of P-H species to alkenes and alkynes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据