期刊
SYNLETT
卷 28, 期 15, 页码 2018-2023出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1588833
关键词
trifluoromethyl beta-diketones; alpha-keto esters; C-C bond cleavage; C-O coupling; alcohols
资金
- National Natural Science Foundation of China [21672151]
A metal-free oxidative coupling reaction of trifluoromethyl beta-diketones with alcohols for the synthesis of alpha-keto esters in good to excellent yields has been developed. Preliminary mechanistic studies suggest that an I-2/TBHP promoted sequential iodination, C-C bond cleavage, C-O bond formation and oxidation pathway is involved in this reaction.
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