4.4 Article

Palladium-Catalyzed Ring-Opening Coupling of Cyclobutenols with Aryl Halides

期刊

SYNLETT
卷 29, 期 6, 页码 754-758

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0036-1589117

关键词

palladium; cyclobutenols; arylation; ring opening; ketones; cross-coupling; condensation; homogeneous catalysis

资金

  1. Grants-in-Aid for Scientific Research [16K05783] Funding Source: KAKEN

向作者/读者索取更多资源

A palladium(0)-catalyzed ring-opening cross-coupling reaction between tert-cyclobutenols and aryl halides produces gamma-arylated beta,gamma-unsaturated ketones. In the case of aryl halides bearing functional groups at the ortho position, the resulting ring-opened ketones undergo intramolecular condensation to afford bicyclic aromatic compounds.

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