期刊
13TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-13
卷 114, 期 -, 页码 1986-1990出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.egypro.2017.03.1332
关键词
NH3 formation; DETA; MDEA; CO2 capture; Emissions; Degradation
资金
- Petroleum and Petrochemical College (PPC), Chulalongkorn University
Ammonia (NH3) is a major volatile degradation product formed from oxidative degradation of diethylenetriamine (DETA), methyldiethanolamine (MDEA), and their blend. Three molars DETA and MDEA were used in their single amine systems while mixture of the two amines using 1.5 M each was also tested. The reaction was operated at 0.65 CO2 loading, 6 % mole O-2, and 393 K. The results indicated that DETA generated NH3 from the oxidative degradation in liquid and gas phases the most, followed by 1.5 M DETA/1.5 M MDEA blend and single MDEA. Crown Copyright (C) 2017 The Authors. Published by Elsevier Ltd.
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