期刊
SUPRAMOLECULAR CHEMISTRY
卷 30, 期 10, 页码 858-868出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/10610278.2017.1406093
关键词
Helicate; cage; spin-crossover; spin-transition
Despite the intense interest in helicate and cage supramolecular architectures, only a small fraction of these are known to switch their spin-state in response to a stimulus, such as temperature and light. However, these have recently emerged as a promising new class of spin-crossover materials and although there are still relatively few examples, it is an active area of research. This review discusses the lessons learned and challenges associated with the design and study of spin-crossover helicates and cages before highlighting new developments in the field. [GRAPHICS] .
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