期刊
ADVANCED SUSTAINABLE SYSTEMS
卷 1, 期 8, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsu.201700067
关键词
activated carbon; ethoxy propylene carbonate; glycerol carbonate; Li-intercalation; lithium-ion capacitors (LICs)
资金
- Boston University
- National Science Foundation [DMR-1507081, DMR-1410450]
The increased number of electrical energy storage (EES) systems utilized in everyday products along with the demand for more reliable and safer products that provide high energy densities with faster response times over an extended range of temperatures are catalyzing advances across all areas of EES technology. Here, the preparation and performance evaluation at 100 degrees C of a high voltage lithium-ion supercapacitor (LIC), comprised of activated carbon electrodes and a novel, environmentally friendly alkyl carbonate electrolyte based on glycerol containing 1 m LiTFSI, are reproted. Use of this ethoxy propylene carbonate electrolyte affords a high capacitance level with notable electrochemical performance including a specific capacitance of 162 F g(-1) at 1 mV s(-1), energy density of 14.2 Wh kg(-1) at 2 A g(-1), and power density of 7.5 kW kg(-1) at 10 A g(-1) at 100 degrees C. The performance of this LIC at 100 degrees C is compared to a conventional ethylene carbonate-dimethyl carbonate LIC operating only at 25 degrees C as conventional organic and aqueous electrolytes do not allow safe operation at such an elevated temperature. Finally, insight into the increased Li+-carbon intercalation mechanism is provided, observed with the system, leading to the enhanced electrochemical performance.
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