期刊
KOREAN CHEMICAL ENGINEERING RESEARCH
卷 55, 期 5, 页码 652-659出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.9713/kcer.2017.55.5.652
关键词
Mineral ions; Optimization; Genetic Algorithms; Extended UNIQUAC Model
In the present research, in order to predict activity coefficient of inorganic ions in electrolyte solution of a petroleum system, we studied 13 components in the electrolyte solution, including H2O, CO2 (aq), H+, Na+, Ba2+, Ca2+, Sr2+, Mg2+, SO4, CO3, OH-, Cl-, and HCO3. To predict the activity coefficient of the components of the petroleum system (a solid/liquid equilibrium system), activity coefficient model of Extended UNIQUAC was studied, along with its adjustable parameters optimized based on a genetic algorithm. The total calculated error associated with optimizing the adjustable parameters of Extended UNIQUAC model considering the 13 components under study at three temperature levels (298.15, 323.15, and 373.15 K) using the genetic algorithm is found to be 0.07.
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