期刊
SMALL
卷 13, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201603938
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类别
资金
- 973 program [2013CB632402]
- NSFC [51320105001, 51372190, 21573170, 51272199, 21433007]
- Self-determined and Innovative Research Funds of SKLWUT [2015-ZD-1]
- NSFHB [2015CFA001]
- Research Foundation of SKLWUT [2015-KF-16]
- Fundamental Research Funds for the Central Universities [WUT: 2015-III-034]
Artificial photosynthesis of hydrocarbon fuels by utilizing solar energy and CO2 is considered as a potential route for solving ever-increasing energy crisis and greenhouse effect. Herein, hierarchical porous O-doped graphitic carbon nitride (g-C3N4) nanotubes (OCN-Tube) are prepared via successive thermal oxidation exfoliation and curling-condensation of bulk g-C3N4. The as-prepared OCN-Tube exhibits hierarchically porous structures, which consist of interconnected multiwalled nanotubes with uniform diameters of 20-30 nm. The hierarchical OCN-Tube shows excellent photocatalytic CO2 reduction performance under visible light, with methanol evolution rate of 0.88 mu mol g(-1) h(-1), which is five times higher than bulk g-C3N4 (0.17 mu mol g(-1) h(-1)). The enhanced photocatalytic activity of OCN-Tube is ascribed to the hierarchical nanotube structure and O-doping effect. The hierarchical nanotube structure endows OCN-Tube with higher specific surface area, greater light utilization efficiency, and improved molecular diffusion kinetics, due to the more exposed active edges and multiple light reflection/scattering channels. The O-doping optimizes the band structure of g-C3N4, resulting in narrower bandgap, greater CO2 affinity, and uptake capacity as well as higher separation efficiency of photogenerated charge carriers. This work provides a novel strategy to design hierarchical g-C3N4 nanostructures, which can be used as promising photocatalyst for solar energy conversion.
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