期刊
SMALL
卷 13, 期 34, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201701260
关键词
cobalt vanadate; current collector; cyclability; high-capacity anodes; lithium ion batteries; porous nickel
类别
资金
- National Key Research and Development Program of China [2017YFA0205700]
- Thousand Youth Talents Plan, the Jiangsu Outstanding Youth Funds [BK20160012]
- National Materials Genome Project [2016YFB0700600]
- Jiangsu Shuangchuang Program
- Nantong Fundamental Research Funds [GY12016040]
A novel spinel Co2VO4 is studied as the Li-ion battery anode material and it is sandwiched with a 3D ultralight porous current collector (PCC) and amorphous carbon. Co2VO4 demonstrates the high capacity and excellent cyclability because of the mixed lithium storage mechanisms. The 3D composite structure requires no binders and replaces the conventional current collector (Cu foil) with a 3D ultralight porous metal scaffold, yielding the high electrode-based capacity. Such a novel composite anode also enables the close adhesion of Co2VO4 to the PCC scaffold. The resulting monolithic electrode has the rapid electron pathway and stable mechanical properties, which lead to the excellent rate capabilities and cycling properties. At a current density of 1 A g(-1), the PCC and carbon sandwiched Co2VO4 anode is able to deliver a stable reversible capacity of about 706.8 mAh g(-1) after 1000 cycles. Generally, this study not only develops a new Co2VO4 anode with high capacity and good cyclability, but also demonstrates an alternative approach to improve the electrochemical properties of high capacity anode materials by using ultralight porous metallic current collector instead of heavy copper foil.
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