期刊
SMALL
卷 13, 期 44, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201702474
关键词
energy storage; graphene oxide; hierarchical porous structure; supercapacitors; thermal reduction
类别
资金
- EPSRC [EP/L018330/1, EP/K002252/1]
- EPSRC [EP/K002252/1, EP/L018330/1] Funding Source: UKRI
Graphene-oxide (GO) based porous structures are highly desirable for supercapacitors, as the charge storage and transfer can be enhanced by advancement in the synthesis. An effective route is presented of, first, synthesis of three-dimensional (3D) assembly of GO sheets in a spherical architecture (GOS) by flash-freezing of GO dispersion, and then development of hierarchical porous graphene (HPG) networks by facile thermal-shock reduction of GOS. This leads to a superior gravimetric specific capacitance of approximate to 306 F g(-1) at 1.0 A g(-1), with a capacitance retention of 93% after 10 000 cycles. The values represent a significant capacitance enhancement by 30-50% compared with the GO powder equivalent, and are among the highest reported for GO-based structures from different chemical reduction routes. Furthermore, a solid-state flexible supercapacitor is fabricated by constructing the HPG with polymer gel electrolyte, exhibiting an excellent areal specific capacitance of approximate to 220 mF cm(-2) at 1.0 mA cm(-2) with exceptional cyclic stability. The work reveals a facile but efficient synthesis approach of GO-based materials to enhance the capacitive energy storage.
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