期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 35, 页码 10587-10591出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201703732
关键词
annulation; cyclopropanes; donor-acceptor systems; naphthoquinone; tin
资金
- European Research Council (ERC Consolidator Grant GAINBYSTRAIN)
Reactions of 2-arylcyclopropane dicarboxylates with naphthoquinones are reported. The key feature was the use of catalytic amounts of SnCl2, which acts as both an electron donor and a Lewis acid. By an in situ umpolung of naphthoquinone the formerly electrophilic species is converted into a nucleophile that is able to trigger the ring-opening of the three-membered ring with formation of a new C-C bond. Treatment of these products with base under oxidative condhions resulted through loss of methyl formate in cyclopenuumulated products with fully conjugated pi Systems exhibiting intensive absorptions in the visible range.
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