期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 35, 页码 10602-10606出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201705403
关键词
macrocycles; nanostructures; polyphenylenes; supramolecular chemistry; synthesis design
资金
- European Research Council grant on NANOGRAPH
- DFG Priority Program Graphene [SPP 1459]
- Max Planck Society
- European Commission through Graphene Flagship
In our search to cluster as many phenylene units as possible in a given space, we have proceeded to the three-dimensional world of benzene-based molecules by employing covalently interlocked cyclohexa-m-phenylenes as present in the unique paddlewheel-shaped polyphenylene 10. A precursor was conceived, in which freely rotating m-chlorophenylene units provide sufficient solubility along with the necessary proximity for the final ring closure to give 10. Monitoring the assembly of solubilized tell-butyl derivatives of 10 into supramolecular carbon nanostructures by dynamic light scattering, (DLS) and Brillouin light scattering (BLS) revealed the dimensions of the initially formed aggregates as well as the antorphous character of the solid state.
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