期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 186, 期 -, 页码 1-9出版社
ELSEVIER
DOI: 10.1016/j.seppur.2017.04.052
关键词
p-NiO/n-TiO2 nano-tube arrays; Photoelectrode; Photoelectrocatalysis; 4-Chlorphenol
资金
- National Natural Science Foundation of China [51508254]
- Nature Science Foundation of Gansu Province of China [1506RJZA216]
- Fundamental Research Funds for the Central Universities [lzujbky-2015-137]
- State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL201509SIC]
- Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials [KFK1502]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lake, Chinese Academy of Sciences
In the study, we report that p-type NiO (p-NiO) nanoparticles were successfully decorated onto the of n-type TiO2 nano-tube arrays (n-TiO2 NTAs) photoelectrode by anodization process, followed by electrodeposition strategy in the presence of NiSO4 electrolyte. After then, the samples were studied by scanning electron microscope (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, the optical and photoelectrochemical (PECH) properties of p-NiO/n-TiO2 NTAs were recorded through ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) curves, respectively. Furthermore, We evaluated the photocatalytic (PC) degradation of 4-chlorphenol and the enhanced PC mechanism was also discussed. Results suggest that p-NiO/n-TiO2 NTAs photoelectrode exhibited higher PC activities than that of pristine TiO2 NTAs owing to its higher photogeneration electrons-holes (e/h(+)) pairs separation efficiency and light absorbance. As a consequence, the p-NiO/n-TiO2 NTAs photoelectrode could be applied in degradation of organic pollutants and wastewater purification. (C) 2017 Elsevier B.V. All rights reserved.
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