期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 241, 期 -, 页码 335-341出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2016.10.092
关键词
Phenanthroimidazole; Fluorescent probe; Hypochlorous acid; High selectivity
资金
- Scientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi [2015173]
In this study, a new compound 2-amino-3-[(4-(1H-phenanthro [9,10-d] imidazol-2-yl) phenyl methylene) amino]-2-butenedinitrile (probe 1) as a simple fluorescent probe for hypochlorous acid has been synthesized and characterized. It exhibited high selectivity and sensitivity as hypochlorite sensor in mixed aqueous medium. NMR and mass spectral analysis showed that the probe reacted with the hypochlorite ion through de-diaminomaleonitrile reaction which disrupted the ICT mechanism by breaking the donor and acceptor linkage resulting in a remarkable enhancement of the emission intensity. In addition, the probe worked excellently within a wide pH range of 4 to 10 and the detection limit was found to be 1.4 x 10(-2) M. The cell experiments showed the good, cell-membrane permeability of probe, and it could be used to image exogenous HOCI. (C) 2016 Elsevier B.V. All rights reserved.
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