期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 241, 期 -, 页码 1324-1330出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2016.09.186
关键词
Carbon dots; Sensor array; Metal ions; Amino acid; Fluorescence
资金
- National Natural Science Foundation of China [21390413, 51425403, 21405090, 91426302]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13026]
- Tsinghua University Initiative Scientific Research Program [2014z22063]
The development of convenient method for detection and identification of toxic metals ions is of great interest. In this work, we have developed a facile fluorescent sensor array based on luminescence carbon dots for detecting and differentiating a set of metal ions. Three kinds of nitrogen-doped carbon dots were synthesized by hydrothermal treatment of citric acid with three different amino acids (L-glycine, L-lysine and L-serine). These carbon dots had various surface states and thus exhibited diverse quenching responses to different metal ions. Six metal ions can be well distinguished at various concentrations (100, 50, 20 and 10 mu M). The discrimination accuracy of unknown samples was found to be 100% at a concentration as low as 10 mu M. In addition, the binary and ternary mixtures of three metal ions (Hg2+, Cu2+, Fe3+) could also be well recognized with this sensor array. This method is simple, label-free, and the sensor arrays could be obtained and expanded easily with large-scale and low-cost. It will broaden the application field of carbon dots sensors and give a new direction of developing sensitive array sensing systems. (C) 2016 Elsevier B.V. All rights reserved.
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