期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 248, 期 -, 页码 940-948出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2017.01.199
关键词
g-C3N4; Graphene; Liquid-phase exfoliation; Protonation; Sensing layer
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2015R1D1A1A01058991, 2016R1A6A1A03012877, 2014R1A1A2059913]
- National Research Foundation of Korea [2014R1A1A2059913, 2015R1D1A1A01058991] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this work, graphitic carbon nitride (g-C3N4) nanosheets were prepared and employed to improve the gas sensitivity performance of graphene. g-C3N4 nanosheets (NS-CN) were exfoliated from bulk powder using a proton-enhanced liquid-phase exfoliation method, where the co-ordinate bonds between nitrogen of g-C3N4 and proton H+ of HCl benefit the swelling of bulk and improve the delamination process. The thickness and size of the exfoliated nanosheets were about 4 nm and 1-2 mu m, respectively. A slight increment of the bandgap of g-C3N4 was observed after exfoliation. It was found that the proton functionalization of g-C3N4 powder before exfoliation facilitates the production of uniform nanosheets. A certain amount ranging from 0% to 90% of as-prepared g-C3N4 was added to a graphene solution and ultrasonically mixed to prepare a graphene/g-C3N4 nanocomposite (G/NS-CN). The performances of pure graphene-based and nanocomposite-based sensors in sensing NO2 gas were systematically investigated and compared. We found compositing g-C3N4 with graphene significantly enhanced the sensing performance of the graphene sensor. A trade-off effect on sensing response was observed as the weight ratio of NS-CN to graphene in the nanocomposite sensor was changed, suggesting the specific roles of g-C3N4 and graphene in sensing behavior. It was found that the nanocomposite sensor with 15 wt% of NS-CN exhibited the best sensing response. The sensor in this optimized composition presented a linear and stable response as well as good recovery toward NO2 gas. The sensing mechanism of the nanocomposite sensor was also proposed. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据