期刊
APPLIED SURFACE SCIENCE
卷 426, 期 -, 页码 1113-1120出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2017.07.302
关键词
Nanoporous gold; Chemical de-alloying; Metallic glass; Raman spectroscopy; Melamine sensing
类别
资金
- Compagnia di San Paolo
- BINGO Project-Torino [2014_L2_146]
- European Commission, Marie Curie Actions - Initial Training Networks (ITN) [607080]
A Au20Cu48Ag7Pd5Si20 metallic glass precursor has been used to synthesize nanoporous gold by chemical de-alloying in a mixture of HNO3 and HF. Gold ligaments of size ranging from 45 to 100 nm were obtained as a function of HNO3 concentration, electrolyte temperature and de-alloying time. The as-prepared nanoporous gold exhibited strong surface enhanced Raman scattering (SERS) effect using 4,4'-bi-pyridine as probe molecule. For application in melamine sensing, the detection limit of 10(-6) M was achieved, which indicated that this biocompatible material has great potential as SERS active substrate. (C) 2017 Elsevier B.V. All rights reserved.
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