期刊
SOLID OXIDE FUEL CELLS 15 (SOFC-XV)
卷 78, 期 1, 页码 905-913出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/07801.0905ecst
关键词
-
资金
- US National Science Foundation [DMR-1506925]
- MRSEC program (NSF) at the Materials Research Center [DMR-1121262]
- International Institute for Nanotechnology (IIN)
- State of Illinois, through the IIN
La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) symmetric-electrode cells with Gd0.1Ce0.9O1.95 (GDC) electrolytes were aged in ambient air at temperatures ranging from 550 to 800 degrees C for times up to 1400 h, without current/polarization. Electrochemical impedance spectroscopy measurements, taken periodically during the tests at a testing temperature of 700 degrees C for cells aged = 700 degrees C, showed a continuous increase in polarization resistance. Focused ion beam-scanning electron microscopy (FIB-SEM) 3D tomography showed that the LSCF electrode did not coarsen measurably even at the highest ageing temperature, 800 degrees C, ruling out LSCF microstructural changes as the mechanism behind the resistance increase. On the other hand, Sr surface segregation, determined by chemical etching with inductively coupled plasma-optical emission spectrometry (ICP-OES) detection, was found to increase with increasing ageing temperature > 650 degrees C. The effect of Sr surface segregation on the oxygen surface exchange and diffusion processes is quantified by comparing the measured electrochemical and microstructural data.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据