期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 32, 期 1, 页码 -出版社
WILEY
DOI: 10.1002/aoc.3906
关键词
amination; Buchwald-Hartwig reaction; C-N coupling reaction; graphene; heterogeneous catalyst; palladium nanoparticles
资金
- Shahid Chamran University of Ahvaz Research Council [1395]
In this work, graphene oxide was functionalized with chitosan (GO-Chit) followed by a simple approach for immobilization of palladium nanoparticles onto a chitosan grafted graphene oxide surface. The Pd-nanocomposite (GO-Chit-Pd) was characterized using Transmission Electron Microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), and X-ray diffraction (XRD) measurements. The catalytic activity of the prepared heterogeneous graphene oxide functionalized chitosan-palladium (GO-Chit-Pd) was investigated in term of C-N coupling reaction (Buchwald-Hartwig amination reaction of aryl halides) yielding products of N-arylamines. The easy purification, convenient operation, and environmental friendliness, combined with a high yield, render this method viable for use in both laboratory research and larger industrial scales. Studying the reusability of the catalyst in this work showed that it could be reused for five times without obvious loss in catalytic activity.
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