4.6 Article

2-Arylation/alkylation of benzothiazoles using superparamagneticgraphene oxide-Fe3O4 hybrid material as a heterogeneous catalystwith diisopropyl azodicarboxylate (DIAD) as an oxidant

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APPLIED ORGANOMETALLIC CHEMISTRY
卷 32, 期 1, 页码 -

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WILEY
DOI: 10.1002/aoc.3971

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Benzothiazoles; DIAD; heterogeneous; hybrid material; magnetic graphene oxide

资金

  1. Shiraz University [95GRD1M235307]

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In this report, we introduced Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites as a heterogeneous catalyst for arylation/alkylation of benzothiazoles with aldehydes and benzylic alcohols in the presence of diisopropyl azodicarboxylate (DIAD) as an oxidant which exclusively produced 2-aryl (alkyl)-1H-benzothizoles in moderate to excellent yields. The absence of precious metals and toxic solvent, easy product isolation, and recyclability of the GO-Fe3O4 with no loss of activity are notable advantages of this method.

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