期刊
SCIENCE CHINA-CHEMISTRY
卷 60, 期 7, 页码 904-911出版社
SCIENCE PRESS
DOI: 10.1007/s11426-016-0442-5
关键词
Lewis base; CO2 adduct; organocatalyst; CO2 transformation; cyclic carbonat
资金
- National Natural Science Foundation of China [21402021]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13008]
- Chang Jiang Scholars Program from Ministry of Education, People's Republic of China [T2011056]
In the recent decade, the development and application of organocatalysis for CO2 transformation into useful chemicals have attracted much attention. Among these organocatalysts, Lewis base-CO2 adducts (LB-CO2) were found to be more efficient. The used Lewis base has great effect on the catalytic activity of its CO2 adduct. This review reports the recent progress in LB-CO2 adducts catalyzed the cyclization of CO2 with epoxides or aziridines to afford cyclic carbonates or oxazolidinones, the carboxylation of CO2 with propargylic alcohols to alpha-alkylidene cyclic carbonates, and the reduction of CO2 to methanol, formamides and methylamines, with the focus on the catalytic mechanism.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据