期刊
ADVANCED FUNCTIONAL MATERIALS
卷 28, 期 5, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201705048
关键词
2D and leaf-like zeolitic imidazolate frameworks; bifunctional air electrodes; cobalt-nitrogen-carbon nanotubes; rechargeable zinc-air batteries
类别
资金
- National Key Research and Development Program of China [2016YFA0202603]
- National Natural Scientific Foundation of China (NSFC) [51372186, 516722040, 21502146]
- Tomsk Polytechnic University Competitiveness Enhancement Program [VIU-316/2017]
Here first a 2D dual-metal (Co/Zn) and leaf-like zeolitic imidazolate framework (ZIF-L)-pyrolysis approach is reported for the low-cost and facile preparation of Co nanoparticles encapsulated into nitrogen-doped carbon nanotubes (Co-N-CNTs). Importantly, the reasonable Co/Zn molar ratio in the ZIF-L is the key to the emergence of the encapsulated microstructure. Specifically, high-dispersed cobalt nanoparticles are fully encapsulated in the tips of N-CNTs, leading to the full formation of highly active Co-N-C moieties for oxygen reduction and evolution reactions (ORR and OER). As a result, the obtained Co-N-CNTs present superior electrocatalytic activity and stability toward ORR and OER over the commercial Pt/C and IrO2 as well as most reported metal-organic-framework-derived catalysts, respectively. Remarkably, as bifunctional air electrodes of the Zn-air battery, it also shows extraordinary charge-discharge performance. The present concept will provide a guideline for screening novel 2D metal-organic frameworks as precursors to synthesize advanced multifunctional nanomaterials for cross-cutting applications.
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