期刊
ASTROPHYSICAL JOURNAL
卷 853, 期 2, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.3847/1538-4357/aaa24e
关键词
astrochemistry; infrared: ISM; ISM: molecules; methods: laboratory: solid state
资金
- VICI grant of NWO (the Netherlands Organization for Scientific Research), an A-ERC [291141]
- NOVA (the Netherlands Research School for Astronomy)
- Royal Netherlands Academy of Arts and Sciences (KNAW)
- European Union's Horizon research and innovation program under the Marie Sklodowska-Curie grant [664931]
- Royal Society
- Holland Research School for Molecular Chemistry (HRSMC)
The astronomical gas-phase detection of simple species and small organic molecules in cold pre-stellar cores, with abundances as high as similar to 10(-8)-10(-9) n(H), contradicts the generally accepted idea that at 10 K, such species should be fully frozen out on grain surfaces. A physical or chemical mechanism that results in a net transfer from solid-state species into the gas phase offers a possible explanation. Reactive desorption, i.e., desorption following the exothermic formation of a species, is one of the options that has been proposed. In astronomical models, the fraction of molecules desorbed through this process is handled as a free parameter, as experimental studies quantifying the impact of exothermicity on desorption efficiencies are largely lacking. In this work, we present a detailed laboratory study with the goal of deriving an upper limit for the reactive desorption efficiency of species involved in the CO-H2CO-CH3OH solid-state hydrogenation reaction chain. The limit for the overall reactive desorption fraction is derived by precisely investigating the solid-state elemental carbon budget, using reflection absorption infrared spectroscopy and the calibrated solid-state band-strength values for CO, H2CO and CH3OH. We find that for temperatures in the range of 10 to 14 K, an upper limit of 0.24 +/- 0.02 for the overall elemental carbon loss upon CO conversion into CH3OH. This corresponds with an effective reaction desorption fraction of <= 0.07 per hydrogenation step, or <= 0.02 per H-atom induced reaction, assuming that H-atom addition and abstraction reactions equally contribute to the overall reactive desorption fraction along the hydrogenation sequence. The astronomical relevance of this finding is discussed.
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