Influence of the Nature of A Cation on Dynamics of Charge Transfer Processes in Perovskite Solar Cells

The electronic processes occurring within the perovskite solar cells (PSCs) are strongly influenced by the nature of the organic A cations present within the inorganic framework. In this study, the impact of FA (CH(NH2)(2)(+)) and Cs+ cations on the intrinsic and interfacial properties in the FAPbBr(3) and CsPbBr3 PSCs is investigated. The analysis of current density (J(SC)) and photovoltage (V-OC) as a function of illumination intensity establishes that the interfacial charge transport is more rapid in FAPbBr(3) devices. Small perturbation measurements including intensity modulated photocurrent and photovoltage spectroscopy are applied to explore the resistive and capacitive elements. Furthermore, electrochemical impedance spectroscopy measurements are found to correlate well with the photovoltaic characteristics of FAPbBr(3) and CsPbBr3 PSCs. Overall, the in-depth analysis of various phenomena occurring within the bromide PSCs allows to underline the working principle, which provides a key to optimize the device performance. The present protocol is not only valid for PSCs but can also be extended to devices based on alternative light harvesters.