期刊
RUSSIAN CHEMICAL BULLETIN
卷 66, 期 4, 页码 661-665出版社
SPRINGER
DOI: 10.1007/s11172-017-1788-6
关键词
allylation; CH acids; palladium complexes; cross-coupling; bis(diphenylphosphino)amines; ligands; phase transfer; Tsuji-Trost reaction
The Tsuji-Trost allylation of CH acids, in particular, those of the YCH2CO2Et type (Y = CO2Et, C(O)Me, CN), with allylic acetates in the K2CO3-DMF system in the presence of palladium catalysts with ligands RN(PPh2)(2) (R = Ph, Pr-i, c-C6H11) is accomplished.
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