期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 360, 期 5, 页码 925-931出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201701348
关键词
Photoredox; Radical; Hantzsch ester; Alkylation
资金
- National Science Foundation of China [21572099, 21332005]
- Natural Science Foundation of Jiangsu Province [BK20151379]
Substituted Hantzsch esters can act as radical reservoirs in photoredox reactions, steadily releasing a carbon radical and a hydrogen atom radical in the absence of an additional electron acceptor. We propose that radical release by substituted Hantzsch esters occurs via a mechanism involving an internal redox cycle. Cinnamidecinnamides, styrenes, alpha,beta-unsaturated acids, and diarylethenes could be alkylated smoothly with these reagents.
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