Contribution of coated humic acids calculated through their surface coverage on nano iron oxides for ofloxacin and norfloxacin sorption

Sorption of organic contaminants on organo-mineral complexes has been investigated extensively, but the sorption contribution of mineral particles was not properly addressed before calculating K-OC, especially for ionic organic contaminants. We measured the surface coverage of a humic acid (HA) on nano iron oxides (n-Fe2O3) in a series of synthesized organo-mineral complexes. The contribution of the coated HA to ofloxacin (OFL) and norfloxacin (NOR) sorption in HA n-Fe2O3 complexes was over 80% of the total sorption with the surface coverage of 36% and foc of 1.6%. All the coated HA showed higher sorption to NOR and OFL in comparison to the original HA, suggesting HA fractionation and/or physical re-conformation during organo-mineral complex formation. The decreased K-OC with multilayer coating may suggest the importance of site-specific interactions for OFL sorption, while the increased K-OC with multilayer coating may suggest the importance of partitioning in hydrophobic region for NOR sorption. (C) 2015 Elsevier Ltd. All rights reserved.