期刊
ENVIRONMENTAL MONITORING AND ASSESSMENT
卷 187, 期 7, 页码 -出版社
SPRINGER
DOI: 10.1007/s10661-015-4629-9
关键词
Hydrazine; Phenol; TiO2 nanoparticles; Chemically modified electrodes
Hydrazine and phenol are two important environmental pollutants. In this work, an electrochemical sensor for the selective and sensitive detection of hydrazine in presence of phenol was developed by the bulk modification of carbon paste electrode (CPE) with TiO2 nanoparticles and Mn(III) salen. Large peak separation, good sensitivity, and stability allow this modified electrode to analyze hydrazine individually and simultaneously along with phenol. Applying square wave voltammetry (SWV), a linear dynamic range of 3 x 10(-8)-4.0 x 10(-4) M with detection limit of 10.0 nM was obtained for hydrazine. Finally, the proposed method was applied to the determination of hydrazine and phenol in some real samples.
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