期刊
REACTIVE & FUNCTIONAL POLYMERS
卷 111, 期 -, 页码 1-6出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.reactfunctpolym.2016.12.007
关键词
Poly(glycidyl methacrylate); High refractive index; Selenium
资金
- National Natural Science Foundation of China [21374067, 21306121]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
- Program of Innovative Research Team of Soochow University
Poly(glycidyl methacrylate) (PGMA) was synthesized by Fe(0)-mediated living radical polymerization followed with post-modification by PhSeZnCl. A series of selenide functionalized PGMAs with different selenium concentrations and molecular weights were obtained. The introduction of selenide groups into PGMA resulted in a polymer with high refractive index. The relationships between the concentration of selenium, degree of polymerization and refractive index were investigated. Results showed that the refractive index of the final polymer could be adjusted by the concentration of selenium and degree of polymerization, which provided a useful way to fabricate polymeric materials with adjustable refractive index. (C) 2016 Elsevier B.V. All rights reserved.
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