期刊
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
卷 74, 期 -, 页码 502-+出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989018003602
关键词
crystal structure; tin(IV) oxalate; N-H center dot center dot center dot O hydrogen bonding; bifurcated N-H center dot center dot center dot(O,O) hydrogen bonds
资金
- Cheikh Anta Diop University, Dakar, Senegal
- CNRS in X-ray Cystallography, Dijon, France
In the title compound, ((Pr2NH2)-Pr-i)(2)[SnI2(C2O4)(2)], which was prepared by reacting ((Pr2NH2+)-Pr-i)(2)center dot C2O42- with SnI4 in a 2:1 molar ratio in a mixed ethanol-acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N-H center dot center dot center dot O and bifurcated N-H center dot center dot center dot(O, O) hydrogen bonds, generating [10 (1) over bar] chains.
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