期刊
ADVANCED SUSTAINABLE SYSTEMS
卷 2, 期 4, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsu.201700122
关键词
ammonia borane; hydrogen storage; nanosizing
资金
- UNSW Internal Research Grant program
- Office of Naval Research [ONRG-NICOP-N62909-16-1-2155]
- Australian Research Council (ARC)-Linkage, Infrastructure, Equipment and Facilities (LIEF) grant at the University of Wollongong [LE120100104]
- Australian Research Council's Future Fellowship funding scheme [FT140100135]
Ammonia borane (AB), with one of the highest hydrogen content (19.6 mass%), has attracted much attention as a potential hydrogen storage material. However, its complex and multistep thermal decomposition process has left the idea that AB can only be an irreversible hydrogen storage material. Herein, we demonstrate the potential of a novel nanosizing strategy in overcoming current drawbacks. By (a) successfully restricting the particle size of AB to the nanoscale (approximate to 50 nm), and (b) discreetly encapsulating the synthesised nanosized AB particles within a nickel (Ni) matrix, AB showed unforeseen hydrogen reversibility along its decomposition path. Owing to the catalytic effect of Ni and the embedment of AB with the Ni matrix, this nanosizing approach reduced the hydrogen release temperature, suppressed the melting of AB and the production of volatiles by-products including diborane and borazine. But more remarkably, this approach enabled the reversible release and uptake of pure hydrogen at 200 degrees C and 6 MPa H-2 pressure, only. Reversibility is thought to occur through an iminoborane oligomer resulting from the initial decomposition of the nanosized AB/Ni matrix. This result demonstrates for the first time the possibility of tailoring.
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