期刊
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
卷 96, 期 5, 页码 1168-1175出版社
WILEY
DOI: 10.1002/cjce.23045
关键词
NH3-SCR; nitrogen oxides; low temperature activity; trace amounts copper; monolithic catalyst
资金
- National High-Tech Research and Development (863) Program of China [2013AA065304]
The selective catalytic reduction of NOx with NH3 (NH3-SCR) activity of 0.10g/g CeO2/WO3-ZrO2-TiO2 (Ce/WZT) in low temperature range was greatly enhanced by the addition of 0.00010g/g Cu (Cu/Ce mass ratio=1:1000). The temperature of complete NOx conversion (T-90) decreased as much as 36 degrees C (from 263 degrees C to 227 degrees C) under a gas hourly space velocity (GHSV) of 30000h(-1). XPS, NH3/O-2-TPD, H-2-TPR, XRD, and FTIR characterizations revealed that the interaction between Cu and Ce, more active oxygen species, stronger NH3 and NO oxidation ability, better redox ability, together with the abundant BrOnsted acid sites contributed to better catalytic activity of 0.00010g/g Cu-0.10g/g Ce/WO3-ZrO2-TiO2 (CC/WZT) catalyst at low temperatures.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据