期刊
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
卷 74, 期 -, 页码 600-+出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989018003857
关键词
crystal structure; Co-parallel to complex with imidazopyridine; noncovalent interactions; supramolecular assembly; Hirshfeld surface; fingerprint plot
资金
- Science and Engineering Research Board (SERB) - Department of Science and Technology (DST), Govt. of India [SB/OS/PDF-524/2015-16]
A new mononuclear tetrahedral Co-parallel to complex, dichloridobis(imidazo[1,2-a]pyridine-KNi)cobalt(II), [CoCl2(C7H6N2)(2)], has been synthesized using a bioactive imidazopyridine ligand. X-ray crystallography reveals that the solidstate structure of the title complex exhibits both C H center dot center dot center dot Cl and pi-pi stacking interactions in building supramolecular assemblies. Indeed, the molecules are linked by C-H center dot center dot center dot Cl interactions into a two-dimensional framework, with finite zero -dimensional dimeric units as building blocks, whereas pi-pi stacking plays a crucial role in building a supramolecular layered network. An exhaustive investigation of the diverse intermolecular interactions via Hirshfeld surface analysis enables contributions to the crystal packing of the title complex to be quantified. The fingerprint plots associated with the Hirshfeld surface clearly display each significant interaction involved in the structure, by quantifying them in an effective visual manner.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据